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• W2988132124 abstract "This study reports two synthetic approaches leading to 2-aminobenzoxazoles and their N-substituted analogues. Our first synthetic strategy involves a reaction between various o-aminophenols and N-cyano-N-phenyl-p-toluenesulfonamide as a nonhazardous electrophilic cyanating agent in the presence of Lewis acid. The second synthetic approach uses the Smiles rearrangement upon activation of benzoxazole-2-thiol with chloroacetyl chloride. Both developed synthetic protocols are widely applicable, afford the desired aminobenzoxazoles in good to excellent yields, and use nontoxic and inexpensive starting material." @default.
• W2988132124 created "2019-11-22" @default.
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• W2988132124 date "2019-11-05" @default.
• W2988132124 modified "2023-10-12" @default.
• W2988132124 title "Synthesis of Various 2-Aminobenzoxazoles: The Study of Cyclization and Smiles Rearrangement" @default.
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• W2988132124 doi "https://doi.org/10.1021/acsomega.9b02702" @default.
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