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- W2988199292 abstract "Abstract A series of dumbbell‐shaped urethane connecting polyoleifinic dendrimers, are synthesized from commercial AB 2 monomer through the concept of post‐generative synthetic induction of novel 1→4‐C branching motif in divergent and convergent growth methodology using carbamoyl chloride reactivity. A synthetic protocol is conducted through the iterative process of O‐ carbamoyl‐allylation of hydroxyls followed by Upjohn dihydroxylation of the allylic double bonds, leading to protection/deprotection free divergent pathway. In parallel, convergent growth route gains dendrimers in relatively good yields. Also, the process of O ‐carbonyloxy‐allylation of [G‐1] polyol affords urethane‐carbonate framework providing access to 1→2‐C branching further. Incorporation of current branching motif results in dendritic scaffold with dense periphery at lower generations itself. Free radical cast polymerization of [G‐0.5] dendrimer with allyl diglycol carbonate (ADC) produces thermoset polymer films, showing good sensitivity and ability to permanently record nuclear tracks." @default.
- W2988199292 created "2019-11-22" @default.
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- W2988199292 date "2019-11-11" @default.
- W2988199292 modified "2023-10-14" @default.
- W2988199292 title "Synthetically Induced 1→4‐C Branching Motif ‐ An Access Towards Dense Urethane Connecting Dendritic Scaffolds and Application in Nuclear Track Detection" @default.
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- W2988199292 doi "https://doi.org/10.1002/slct.201903243" @default.
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