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• W2988498558 endingPage "25801" @default.
• W2988498558 startingPage "25797" @default.
• W2988498558 abstract "The phenyltelluryl radical was prepared by high-vacuum flash pyrolysis of diphenyl ditelluride and was chacracterized by matrix isolation IR and UV/Vis spectroscopy. After doping the matrix with molecular oxygen and allowing bimolecular reactions, the hitherto unkown phenyltelluro peroxy radical formed and was identified via IR spectroscopy. Irradiation with light at λ = 436 nm leads to isomerization to the thermodynamically more stable novel phenyltelluroyl radical. All experimental findings agree well with density functional theory (UB3LYP/Def2QZVPP and UM06-2X/Def2QZVPP) computations." @default.
• W2988498558 created "2019-11-22" @default.
• W2988498558 creator A5027412086 @default.
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• W2988498558 creator A5048316760 @default.
• W2988498558 date "2019-01-01" @default.
• W2988498558 modified "2023-10-16" @default.
• W2988498558 title "Spectroscopic identification of the phenyltelluryl radical and its reactivity toward molecular oxygen" @default.
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• W2988498558 doi "https://doi.org/10.1039/c9cp05112k" @default.
• W2988498558 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31728465" @default.
• W2988498558 hasPublicationYear "2019" @default.
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