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- W2989277922 abstract "The results of spectral studies of a series of zinc(II) complexes with alkyl and halogen substituted dipyrromethenes (HL) of the composition [ZnL2] in binary mixtures of cyclohexane with various additives of proton and electron donating co-solvents (acetone, ethanol, N,N-dimethylformamide, pyridine, diethylamine and triethylamine) were presented. The influence of polarity and electron-donating ability of the co-solvent and the functionalization features of dipyrromethene ligands on the fluorescence quenching efficiency of luminophores [ZnL2] was discussed. Found that [ZnL2] with dibromo-substituted ligands exhibits the highest sensitivity of the fluorescence characteristics to the presence of proton- and electron donor analytes in comparison with alkyl substituted analogues. The obtained results allow to offer zinc(II) dipyrromethenates as new, highly sensitive and selective fluorescent «On-Off» sensors of the O- and N-containing toxicants (up to ~ 8 ∙ 10−6 mol/l) in organic media." @default.
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- W2989277922 date "2020-01-01" @default.
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- W2989277922 title "Influence of structural factors and medium properties on the fluorescence of alkyl and halogen substituted zinc(II) dipyrromethenates" @default.
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- W2989277922 doi "https://doi.org/10.1016/j.molliq.2019.112026" @default.
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