FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2989499420> ?p ?o ?g. }

• W2989499420 endingPage "115299" @default.
• W2989499420 startingPage "115299" @default.
• W2989499420 abstract "The formation of carcinogenic N-nitrosamines from reactions between solvent amines and flue gas NOx is an important concern for the application of amine-based processes to capture CO2 post-combustion. Using an advanced test rig with interconnected absorber and desorber units, we evaluated the importance for N-nitrosamine formation of the desorber relative to the absorber, and any synergism between the two units. Variations in desorber temperature and in flue gas composition indicated that N-nitrosamine formation from fresh monoethanolamine (MEA) occurred predominantly in the absorber. N-nitrosamine formation was driven by high NO2 and O2 flue gas concentrations, although NO also contributed. In contrast, N-nitrosamine formation from piperazine (PZ) was driven by reactions with nitrite in the heated desorber, and accelerated concurrent with nitrite accumulation. A complementary experiment simulating aged MEA solvent (high nitrite, 1.5% sarcosine as a proxy of secondary amine degradation products) suggested the desorber becomes an order of magnitude more important than the absorber for N-nitrosamine formation. For fresh MEA solvent, increasing the desorber temperature from 110 °C to 130 °C promoted thermal decomposition of N-nitrosamines, reducing N-nitrosamine accumulation rates two-fold. Compared to the test rig, the prevailing practice of using separate absorber columns and autoclave-like treatments to mimic desorber units predicted the direction, but underestimated the magnitude of N-nitrosamine formation. Because N-nitrosamine accumulation rates are the net result of competing formation and thermal decomposition processes, use of continuously cycling test rigs may be necessary to understand the impacts of different operating conditions." @default.
• W2989499420 created "2019-11-22" @default.
• W2989499420 creator A5015188538 @default.
• W2989499420 creator A5045123804 @default.
• W2989499420 creator A5045203793 @default.
• W2989499420 date "2020-03-01" @default.
• W2989499420 modified "2023-09-24" @default.
• W2989499420 title "Role of absorber and desorber units and operational conditions for N-nitrosamine formation during amine-based carbon capture" @default.
• W2989499420 cites W1964749557 @default.
• W2989499420 cites W1965678206 @default.
• W2989499420 cites W1974789605 @default.
• W2989499420 cites W1976459807 @default.
• W2989499420 cites W1978638880 @default.
• W2989499420 cites W1984740192 @default.
• W2989499420 cites W1988302842 @default.
• W2989499420 cites W1990970263 @default.
• W2989499420 cites W1991754699 @default.
• W2989499420 cites W1992384367 @default.
• W2989499420 cites W1998967829 @default.
• W2989499420 cites W2003666522 @default.
• W2989499420 cites W2004425201 @default.
• W2989499420 cites W2010082959 @default.
• W2989499420 cites W2018066740 @default.
• W2989499420 cites W2021648996 @default.
• W2989499420 cites W2043804740 @default.
• W2989499420 cites W2047267519 @default.
• W2989499420 cites W2050292163 @default.
• W2989499420 cites W2052858466 @default.
• W2989499420 cites W2058065636 @default.
• W2989499420 cites W2063570106 @default.
• W2989499420 cites W2063586831 @default.
• W2989499420 cites W2069925783 @default.
• W2989499420 cites W2076949647 @default.
• W2989499420 cites W2079875644 @default.
• W2989499420 cites W2082247841 @default.
• W2989499420 cites W2085563020 @default.
• W2989499420 cites W2089037194 @default.
• W2989499420 cites W2145009485 @default.
• W2989499420 cites W2150390047 @default.
• W2989499420 cites W2162745615 @default.
• W2989499420 cites W2191239686 @default.
• W2989499420 cites W2313127483 @default.
• W2989499420 cites W2319266827 @default.
• W2989499420 cites W2322448833 @default.
• W2989499420 cites W2323013313 @default.
• W2989499420 cites W2323561662 @default.
• W2989499420 cites W2333200482 @default.
• W2989499420 cites W2333410227 @default.
• W2989499420 cites W2334130150 @default.
• W2989499420 cites W2409326622 @default.
• W2989499420 cites W2433897258 @default.
• W2989499420 cites W2622236899 @default.
• W2989499420 cites W2742509781 @default.
• W2989499420 cites W2748497269 @default.
• W2989499420 cites W2750115336 @default.
• W2989499420 cites W2757780399 @default.
• W2989499420 cites W2767848193 @default.
• W2989499420 cites W2780051361 @default.
• W2989499420 cites W2897999393 @default.
• W2989499420 cites W2900837654 @default.
• W2989499420 cites W2910489163 @default.
• W2989499420 cites W2957408954 @default.
• W2989499420 cites W3198959355 @default.
• W2989499420 cites W658736769 @default.
• W2989499420 doi "https://doi.org/10.1016/j.watres.2019.115299" @default.
• W2989499420 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31760360" @default.
• W2989499420 hasPublicationYear "2020" @default.
• W2989499420 type Work @default.
• W2989499420 sameAs 2989499420 @default.
• W2989499420 citedByCount "3" @default.
• W2989499420 countsByYear W29894994202020 @default.
• W2989499420 countsByYear W29894994202022 @default.
• W2989499420 crossrefType "journal-article" @default.
• W2989499420 hasAuthorship W2989499420A5015188538 @default.
• W2989499420 hasAuthorship W2989499420A5045123804 @default.
• W2989499420 hasAuthorship W2989499420A5045203793 @default.
• W2989499420 hasConcept C105923489 @default.
• W2989499420 hasConcept C107872376 @default.
• W2989499420 hasConcept C114246631 @default.
• W2989499420 hasConcept C131779359 @default.
• W2989499420 hasConcept C167206829 @default.
• W2989499420 hasConcept C178790620 @default.
• W2989499420 hasConcept C179104552 @default.
• W2989499420 hasConcept C185592680 @default.
• W2989499420 hasConcept C203032635 @default.
• W2989499420 hasConcept C2776179834 @default.
• W2989499420 hasConcept C2776384668 @default.
• W2989499420 hasConcept C2777395278 @default.
• W2989499420 hasConcept C2780471494 @default.
• W2989499420 hasConceptScore W2989499420C105923489 @default.
• W2989499420 hasConceptScore W2989499420C107872376 @default.
• W2989499420 hasConceptScore W2989499420C114246631 @default.
• W2989499420 hasConceptScore W2989499420C131779359 @default.
• W2989499420 hasConceptScore W2989499420C167206829 @default.
• W2989499420 hasConceptScore W2989499420C178790620 @default.
• W2989499420 hasConceptScore W2989499420C179104552 @default.
• W2989499420 hasConceptScore W2989499420C185592680 @default.
• W2989499420 hasConceptScore W2989499420C203032635 @default.

• next