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- W2989508760 abstract "The inside cover picture, designed by Xiaoyi Tong, Qilin Wang and co-workers, illustrate an unexpected BF3⋅OEt2-catalyzed Michael addition/cyclization/dehydration sequence of ortho-hydroxyenaminones with aldehyde-derived β,γ-unsaturated α-ketoesters, which afforded a wide range of fused hydrogenated benzoxazole polycycles in 67-95% yields in a highly diastereoselective manner. When isatin-derived β,γ-unsaturated α-ketoesters were employed, completely different reactivities were observed, delivering an array of new atropisomers with an oxindole-substituted N-C axially chiral pyrrole-phenol backbone in up to 97% yield. Details of this work can be found in the communication on pages 4893–4901 (X. Bai, L. Wang, Z. Zhang, K. Zhang, Z. Bu, Y. Wu, W. Zhang, Q. Wang, Adv. Synth. Catal. 2019, 361, 4893–4901; DOI: 10.1002/adsc.201900950)." @default.
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- W2989508760 date "2019-10-22" @default.
- W2989508760 modified "2023-09-25" @default.
- W2989508760 title "Cover Picture: Unexpected Cascade Reactions of Ortho ‐Hydroxyenaminones and β,γ‐Unsaturated α‐Ketoesters to Access Hydrogenated Benzoxazolepolycycles and Pyrrole−Phenol Atropisomers (Adv. Synth. Catal. 21/2019)" @default.
- W2989508760 doi "https://doi.org/10.1002/adsc.201901313" @default.
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