Matches in SemOpenAlex for { <https://semopenalex.org/work/W2989653167> ?p ?o ?g. }
- W2989653167 endingPage "1551" @default.
- W2989653167 startingPage "1548" @default.
- W2989653167 abstract "Abstract Applications of zeolites in catalysis are plagued by strong diffusion resistance, which results from limitations to molecular transport in micropores, across external crystal surfaces, but also across internal interfaces. The first type of diffusion resistance is well understood, the second is receiving increasing attention, while the diffusion barriers at internal interfaces remain largely unclear. We take Pt/Beta catalyzed isomerization of n ‐heptane as the model system to explore the role of internal diffusion barriers in zeolite catalysis. The two as‐synthesized Pt/Beta catalysts have an identical Pt loading, similar Beta particle size and acidity, but different internal structures. A Pt/Beta crystal with no observable internal interfaces can be 180 % higher in activity and 22 % higher in selectivity than its counterpart with numerous internal interfaces. This can only be attributed to the strong transport barriers across internal interfaces, as supported by directly comparing the apparent diffusivities of the two Beta samples." @default.
- W2989653167 created "2019-12-05" @default.
- W2989653167 creator A5001049781 @default.
- W2989653167 creator A5008756247 @default.
- W2989653167 creator A5022526821 @default.
- W2989653167 creator A5026730990 @default.
- W2989653167 creator A5042349571 @default.
- W2989653167 creator A5075419176 @default.
- W2989653167 date "2019-12-04" @default.
- W2989653167 modified "2023-10-18" @default.
- W2989653167 title "Understanding the Role of Internal Diffusion Barriers in Pt/Beta Zeolite Catalyzed Isomerization of <i>n</i>‐Heptane" @default.
- W2989653167 cites W1963794009 @default.
- W2989653167 cites W1963879758 @default.
- W2989653167 cites W1972989023 @default.
- W2989653167 cites W1982781046 @default.
- W2989653167 cites W1983308508 @default.
- W2989653167 cites W2004372604 @default.
- W2989653167 cites W2022229696 @default.
- W2989653167 cites W2033349412 @default.
- W2989653167 cites W2035139888 @default.
- W2989653167 cites W2035662067 @default.
- W2989653167 cites W2040884140 @default.
- W2989653167 cites W2053746350 @default.
- W2989653167 cites W2054111649 @default.
- W2989653167 cites W2064116739 @default.
- W2989653167 cites W2074721138 @default.
- W2989653167 cites W2075045251 @default.
- W2989653167 cites W2091118296 @default.
- W2989653167 cites W2108442558 @default.
- W2989653167 cites W2108929900 @default.
- W2989653167 cites W2119192520 @default.
- W2989653167 cites W2130687103 @default.
- W2989653167 cites W2137044267 @default.
- W2989653167 cites W2254903655 @default.
- W2989653167 cites W2281546031 @default.
- W2989653167 cites W2300918420 @default.
- W2989653167 cites W2312530585 @default.
- W2989653167 cites W2478317772 @default.
- W2989653167 cites W2737530672 @default.
- W2989653167 cites W2753551387 @default.
- W2989653167 cites W2793178742 @default.
- W2989653167 cites W2807734441 @default.
- W2989653167 cites W2936192491 @default.
- W2989653167 cites W2965502943 @default.
- W2989653167 cites W4238349666 @default.
- W2989653167 cites W4251847947 @default.
- W2989653167 cites W4253089763 @default.
- W2989653167 doi "https://doi.org/10.1002/anie.201913660" @default.
- W2989653167 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31750968" @default.
- W2989653167 hasPublicationYear "2019" @default.
- W2989653167 type Work @default.
- W2989653167 sameAs 2989653167 @default.
- W2989653167 citedByCount "35" @default.
- W2989653167 countsByYear W29896531672020 @default.
- W2989653167 countsByYear W29896531672021 @default.
- W2989653167 countsByYear W29896531672022 @default.
- W2989653167 countsByYear W29896531672023 @default.
- W2989653167 crossrefType "journal-article" @default.
- W2989653167 hasAuthorship W2989653167A5001049781 @default.
- W2989653167 hasAuthorship W2989653167A5008756247 @default.
- W2989653167 hasAuthorship W2989653167A5022526821 @default.
- W2989653167 hasAuthorship W2989653167A5026730990 @default.
- W2989653167 hasAuthorship W2989653167A5042349571 @default.
- W2989653167 hasAuthorship W2989653167A5075419176 @default.
- W2989653167 hasBestOaLocation W29896531672 @default.
- W2989653167 hasConcept C121332964 @default.
- W2989653167 hasConcept C126661725 @default.
- W2989653167 hasConcept C127413603 @default.
- W2989653167 hasConcept C147789679 @default.
- W2989653167 hasConcept C159467904 @default.
- W2989653167 hasConcept C161790260 @default.
- W2989653167 hasConcept C175583648 @default.
- W2989653167 hasConcept C178790620 @default.
- W2989653167 hasConcept C185592680 @default.
- W2989653167 hasConcept C192562407 @default.
- W2989653167 hasConcept C199360897 @default.
- W2989653167 hasConcept C2777854178 @default.
- W2989653167 hasConcept C2778077586 @default.
- W2989653167 hasConcept C2781285689 @default.
- W2989653167 hasConcept C41008148 @default.
- W2989653167 hasConcept C42360764 @default.
- W2989653167 hasConcept C69357855 @default.
- W2989653167 hasConcept C97355855 @default.
- W2989653167 hasConceptScore W2989653167C121332964 @default.
- W2989653167 hasConceptScore W2989653167C126661725 @default.
- W2989653167 hasConceptScore W2989653167C127413603 @default.
- W2989653167 hasConceptScore W2989653167C147789679 @default.
- W2989653167 hasConceptScore W2989653167C159467904 @default.
- W2989653167 hasConceptScore W2989653167C161790260 @default.
- W2989653167 hasConceptScore W2989653167C175583648 @default.
- W2989653167 hasConceptScore W2989653167C178790620 @default.
- W2989653167 hasConceptScore W2989653167C185592680 @default.
- W2989653167 hasConceptScore W2989653167C192562407 @default.
- W2989653167 hasConceptScore W2989653167C199360897 @default.
- W2989653167 hasConceptScore W2989653167C2777854178 @default.
- W2989653167 hasConceptScore W2989653167C2778077586 @default.
- W2989653167 hasConceptScore W2989653167C2781285689 @default.
- W2989653167 hasConceptScore W2989653167C41008148 @default.