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• W2989740424 abstract "A xanthate RAFT agent 2-isopropyl-5-methylcyclohexyl 2-(ethoxycarbonothioyl)thio) propanoate has been synthesized via the reactions of L-menthol with 2-bromo-propionyl bromide in THF in the presence of triethylamine leading to the formation of 2-isopropyl-5-methylcyclohexyl 2-bromopropanoate followed by its reaction with potassium-O-ethyl xanthate in ethanol at room temperature and characterized by 1H, 13C NMR and FTIR. RAFT polymerization of vinyl acetate (VAc) using it has resulted in the formation of well-defined polyVAc in controlled manner. This is evidenced by (i) the observation of the pseudo first order kinetics upto ∼90% conversion, (ii) linear increment of molecular weight (unimodal GPC chromatogram) of the polymer keeping its PDI low with the progress of the reaction upto ∼90% conversion, (iii) the linear increment of the molecular weight of the polymers with low PDI on increasing monomer loading, (iv) chain-end analysis of the polymer using 1H NMR confirming the presence of the RAFT agent fragment at the polymer chain-ends, and (v) successful homo- and hetero-chain extension with VAc and NVP, respectively. L-Menthyl-capped polyvinyl acetate has shown higher (i) light transmission properties of its dichloromethane solution at ∼277 nm, (ii) thermal stability, and (iii) glass transition temperature in comparison to its non-L-Menthyl-capped homolog." @default.
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• W2989740424 date "2019-11-23" @default.
• W2989740424 modified "2023-09-27" @default.
• W2989740424 title "L-menthol-based xanthate mediator for RAFT polymerization of vinyl acetate" @default.
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• W2989740424 doi "https://doi.org/10.1080/10601325.2019.1691457" @default.
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