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• W2989742511 abstract "Herein, the impact of alkyl bridge length is unraveled on the self-assembly of N-annulated perylenetetracarboxamides 1–4 that cooperatively form supramolecular polymers. Spectroscopic studies in different solvents as media for the self-assembly demonstrate the impact that the length of the bridge separating the two amide groups of compounds 1–4 exerts on the supramolecular polymerization process: i) in MCH/Tol (8/2), compounds 1–3 exhibit a consecutive process that, however, it is not operative for 4; ii) the presence of three methylene units in 2, which can induce a parallel distribution of the amide groups, notably decreases the stability of the corresponding aggregates in Tol; iii) increasing the spacer length accelerates the conversion of the metastable, intramolecularly H-bonded monomeric species, which prevents to develop seeded supramolecular polymerizations; iv) the presence of a spacer with five methylene units in 4 hinders the formation of the corresponding 10-membered pseudo-cycle; and v) only the higher relative stability of the inactivated monomeric species of 1 enables pathway complexity, with a kinetically controlled self-assembly to yield nanoparticles and a thermodynamically controlled supramolecular polymerization to achieve fibrillar structures. The results presented herein expand the knowledge on the structure/property relationship for self-assembling units to provide pathway complexity and to bias the kinetics and stability of the supramolecular aggregates." @default.
• W2989742511 created "2019-12-05" @default.
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• W2989742511 date "2019-11-26" @default.
• W2989742511 modified "2023-10-09" @default.
• W2989742511 title "Alkyl Bridge Length to Bias the Kinetics and Stability of Consecutive Supramolecular Polymerizations" @default.
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• W2989742511 doi "https://doi.org/10.1002/smtd.201900715" @default.
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