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- W2989743043 abstract "Recently, multivalent aqueous calcium-ion batteries (CIBs) have attracted considerable attention as a possible alternative to Li-ion batteries. However, traditional Ca-ion storage materials show either limited rate capabilities and poor cycle life or insufficient specific capacity. Here, we tackle these limitations by exploring materials having a large interlayer distance to achieve decent specific capacities and one-dimensional architecture with adequate Ca-ion passages that enable rapid reversible (de)intercalation processes. In this work, we report the high-yield, rapid, and low-cost synthesis of 1D metal oxides <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:mi>M</mml:mi> </mml:math> V 3 O 8 ( <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML overflow=scroll> <mml:mi>M</mml:mi> <mml:mo>=</mml:mo> <mml:mtext>Li</mml:mtext> </mml:math> , K), CaV 2 O 6 , and CaV 6 O 16 ·7H 2 O (CVO) via a molten salt method. Firstly, using 1D CVO as electrode materials, we show high capacity 205 mA h g -1 , long cycle life (>97% capacity retention after 200 cycles at 3.0 C), and high-rate performance (117 mA h g -1 at 12 C) for Ca-ion (de)intercalation. This work represents a step forward for the development of the molten salt method to synthesize nanomaterials and to help pave the way for the future growth of Ca-ion batteries." @default.
- W2989743043 created "2019-12-05" @default.
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- W2989743043 date "2019-01-01" @default.
- W2989743043 modified "2023-10-10" @default.
- W2989743043 title "Ultrafast Synthesis of Calcium Vanadate for Superior Aqueous Calcium-Ion Battery" @default.
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- W2989743043 doi "https://doi.org/10.34133/2019/6585686" @default.
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