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- W2990086158 abstract "The corrosion behavior and mechanism of Inconel 600 exposed to the oxidizing high-salinity supercritical water (SCW) containing chlorides, sulfates, and phosphates at 450, 500, and 580 °C were investigated and proposed. The corrosion film had an outer layer dominated by NiO, Fe₂O₃, and eutectic phosphate deposit and an inner layer consisting of Cr-rich oxides. Some produced oxides may generate ionic reactions with the low-melting phosphates precipitated out from SCW, triggering the generation of the eutectic FePO₄–Ni₃(PO₄)₂–Na₃PO₄–Na₂HPO₄ salts in the outer layer. The formation and thickening of the outer layer results from the eutectic phosphate disposition and the common solid-state growth mechanism. Nonmolten chlorides and sulfates in SCW predominantly exist on the outmost surface and are easily washed off, being supported by the absence of S and Cl on sample surfaces. Based on this investigation, a comprehensive corrosion mechanism, involving the solid-state growth of oxide scales, salt precipitation, and phosphate melting processes, was proposed and discussed." @default.
- W2990086158 created "2019-12-05" @default.
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- W2990086158 date "2019-11-22" @default.
- W2990086158 modified "2023-09-24" @default.
- W2990086158 title "Corrosion Mechanism of Inconel 600 in Oxidizing Supercritical Aqueous Systems Containing Multiple Salts" @default.
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- W2990086158 doi "https://doi.org/10.1021/acs.iecr.9b04527" @default.
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