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- W2990185008 abstract "Abstract This review provides an update on the progress in understanding formation and degradation mechanisms in halide perovskites for photovoltaic applications, as supported by in situ and operando X‐ray scattering techniques. The value of these real‐time analyses is particularly high for gaining insights into the structural evolution during crystal formation and decomposition upon exposure to external stress factors. This type of analysis reveals the pathways between starting and end points of a process rather than being limited to comparing states before and after the process. Special attention is put on the successful efforts toward upscaling including deposition techniques that are compatible to roll‐to‐roll processing. These processes are realized using fast annealing procedures. The development of these processes strongly benefited from in situ studies exploring the direct transition from precursor to perovskite without going through observable crystalline intermediate phases. A particular focus of this review is the benefit of using in situ and operando X‐ray scattering techniques to better understand and ultimately improve device stability. The difference between structural stability of thin films and structural stability under device operation is highlighted, convincingly demonstrating the indispensability of operando studies." @default.
- W2990185008 created "2019-12-05" @default.
- W2990185008 creator A5004643547 @default.
- W2990185008 creator A5044652862 @default.
- W2990185008 date "2019-11-25" @default.
- W2990185008 modified "2023-10-16" @default.
- W2990185008 title "Structural Evolution During Perovskite Crystal Formation and Degradation: In Situ and Operando X‐Ray Diffraction Studies" @default.
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- W2990185008 doi "https://doi.org/10.1002/aenm.201903074" @default.
- W2990185008 hasPublicationYear "2019" @default.
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