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• W2990321330 startingPage "1084" @default.
• W2990321330 abstract "Despite the importance of cell wall diffusion to nearly all aspects of wood utilization, diffusion mechanisms and the detailed effects of moisture remain poorly understood. In this perspective, we introduce and employ approaches established in polymer science to develop a phenomenological framework for understanding the effects of moisture on diffusion in unmodified wood cell walls. The premise for applying this polymer-science-based approach to wood is that wood polymers (cellulose, hemicelluloses, and lignin) behave like typical solid polymers. Therefore, the movement of chemicals through wood cell walls is a diffusion process through a solid polymer, which is in contrast to previous assertions that transport of some chemicals occurs via aqueous pathways in the cell wall layers. Diffusion in polymers depends on the interrelations between free volume in the polymer matrix, molecular motions of the polymer, diffusant dimensions, and solubility of the diffusant in the polymer matrix. Because diffusion strongly depends on whether a polymer is in a rigid glassy state or soft rubbery state, it is important to understand glass transitions in the amorphous wood polymers. Through a review and analysis of available literature, we conclude that in wood both lignin and the amorphous polysaccharides very likely have glass transitions. After developing and presenting this polymer-science-based perspective of diffusion through unmodified wood cell walls, suggested directions for future research are discussed. A key consideration is that a large difference between diffusion through wood polymers and typical polymers is the high swelling pressures that can develop in unmodified wood cell walls. This pressure likely arises from the hierarchical structure of wood and should be taken into consideration in the development of predictive models for diffusion in unmodified wood cell walls." @default.
• W2990321330 created "2019-12-05" @default.
• W2990321330 creator A5028174961 @default.
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• W2990321330 creator A5090805468 @default.
• W2990321330 date "2019-11-29" @default.
• W2990321330 modified "2023-10-15" @default.
• W2990321330 title "Effects of Moisture on Diffusion in Unmodified Wood Cell Walls: A Phenomenological Polymer Science Approach" @default.
• W2990321330 cites W115686878 @default.
• W2990321330 cites W136023567 @default.
• W2990321330 cites W1493573062 @default.
• W2990321330 cites W1507805306 @default.
• W2990321330 cites W1538226806 @default.
• W2990321330 cites W1570065020 @default.
• W2990321330 cites W1964498130 @default.
• W2990321330 cites W1965194542 @default.
• W2990321330 cites W1966515503 @default.
• W2990321330 cites W1967483201 @default.
• W2990321330 cites W1968268700 @default.
• W2990321330 cites W1972675654 @default.
• W2990321330 cites W1974527015 @default.
• W2990321330 cites W1974823387 @default.
• W2990321330 cites W1975300282 @default.
• W2990321330 cites W1975403376 @default.
• W2990321330 cites W1981641451 @default.
• W2990321330 cites W1983194148 @default.
• W2990321330 cites W1986113254 @default.
• W2990321330 cites W1988688863 @default.
• W2990321330 cites W1989026034 @default.
• W2990321330 cites W1991083892 @default.
• W2990321330 cites W1995779377 @default.
• W2990321330 cites W1996016803 @default.
• W2990321330 cites W1997376914 @default.
• W2990321330 cites W1997892945 @default.
• W2990321330 cites W1998501224 @default.
• W2990321330 cites W1999392279 @default.
• W2990321330 cites W2000213969 @default.
• W2990321330 cites W2000666541 @default.
• W2990321330 cites W2001586564 @default.
• W2990321330 cites W2003153091 @default.
• W2990321330 cites W2003784655 @default.
• W2990321330 cites W2006885723 @default.
• W2990321330 cites W2006994463 @default.
• W2990321330 cites W2007441729 @default.
• W2990321330 cites W2007497419 @default.
• W2990321330 cites W2007753739 @default.
• W2990321330 cites W2008002053 @default.
• W2990321330 cites W2009432927 @default.
• W2990321330 cites W2011244774 @default.
• W2990321330 cites W2011254969 @default.
• W2990321330 cites W2013996700 @default.
• W2990321330 cites W2014450350 @default.
• W2990321330 cites W2015946080 @default.
• W2990321330 cites W2016699015 @default.
• W2990321330 cites W2017050492 @default.
• W2990321330 cites W2018523256 @default.
• W2990321330 cites W2020892490 @default.
• W2990321330 cites W2021205507 @default.
• W2990321330 cites W2024408259 @default.
• W2990321330 cites W2026803952 @default.
• W2990321330 cites W2027138928 @default.
• W2990321330 cites W2028815423 @default.
• W2990321330 cites W2030001918 @default.
• W2990321330 cites W2031208876 @default.
• W2990321330 cites W2036601390 @default.
• W2990321330 cites W2037939656 @default.
• W2990321330 cites W2040059511 @default.
• W2990321330 cites W2040670615 @default.
• W2990321330 cites W2041796713 @default.
• W2990321330 cites W2042928639 @default.
• W2990321330 cites W2043296479 @default.
• W2990321330 cites W2044436500 @default.
• W2990321330 cites W2046599847 @default.
• W2990321330 cites W2047007777 @default.
• W2990321330 cites W2050228560 @default.
• W2990321330 cites W2050567117 @default.
• W2990321330 cites W2050637435 @default.
• W2990321330 cites W2050960197 @default.
• W2990321330 cites W2051398185 @default.
• W2990321330 cites W2051824356 @default.
• W2990321330 cites W2055922361 @default.
• W2990321330 cites W2057908234 @default.
• W2990321330 cites W2059787456 @default.
• W2990321330 cites W2060186409 @default.
• W2990321330 cites W2061056084 @default.
• W2990321330 cites W2064762414 @default.
• W2990321330 cites W2067372042 @default.
• W2990321330 cites W2072177177 @default.
• W2990321330 cites W2073669913 @default.
• W2990321330 cites W2074232369 @default.
• W2990321330 cites W2076732651 @default.
• W2990321330 cites W2078877907 @default.
• W2990321330 cites W2081759920 @default.
• W2990321330 cites W2083258536 @default.
• W2990321330 cites W2084146913 @default.
• W2990321330 cites W2084195394 @default.

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