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- W2990429692 endingPage "19878" @default.
- W2990429692 startingPage "19870" @default.
- W2990429692 abstract "Chiral α- and β-aminoboronic acids exhibit unique biological activities. General methods for the synthesis of these bioisosteres of amino acids are highly desirable. We report a facile preparation of these compounds through rhodium-catalyzed regiodivergent and enantioselective hydroboration of enamides. Catalytic asymmetric synthesis of α- and β-aminoboronic esters with high regio-, diastereo-, and enantioselectivities were achieved through effective catalyst control and tuning substrate geometry. Starting from easily available materials, this strategy provides a unified synthetic access to both enantioenriched α-boration and β-boration products. The synthetic utility of these methods was demonstrated by efficient synthesis of an anticancer drug molecule and diverse transformations of the boration products." @default.
- W2990429692 created "2019-12-05" @default.
- W2990429692 creator A5008663016 @default.
- W2990429692 creator A5012025359 @default.
- W2990429692 creator A5073563274 @default.
- W2990429692 creator A5083004837 @default.
- W2990429692 date "2019-11-20" @default.
- W2990429692 modified "2023-10-15" @default.
- W2990429692 title "Rhodium-Catalyzed Regiodivergent and Enantioselective Hydroboration of Enamides" @default.
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