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• W2990524491 abstract "The oxygen vacancyprofile in LaCoO3 exhibits rich phaseswith distinct structures, symmetries, and magnetic properties. Explorationof the lattice degree of freedom of LaCoO3 in the transitionbetween these different structural phases may provide a route to enablenew functionality in oxide materials with potential applications.To date, the oxygen vacancy profile transition in LaCoO3 has mainly been induced by transition-metal doping or thermal treatment.Epitaxial strain was proposed to compete with the lattice degree offreedom but has not yet been rationalized. Here, the experimentalfindings of strain-inhibited structural transition from perovskiteto brownmillerite during the electromigration of oxygen vacanciesin epitaxial LaCoO3 thin films are demonstrated. The resultsindicate that the oxygen vacancy ordering phase induced by the electricfield is suppressed locally by both epitaxial strain field and externalloads shown by in situ aberration-corrected (scanning)/transmission electron microscopy. The demonstrated complex interplaybetween the electric and strain fields in the structural transitionsof LaCoO3 opens up prospects for manipulating new physicalproperties by external excitations and/or strain engineering of asubstrate." @default.
• W2990524491 created "2019-12-05" @default.
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• W2990524491 date "2019-09-20" @default.
• W2990524491 modified "2023-09-26" @default.
• W2990524491 title "Strain-InhibitedElectromigration of Oxygen Vacanciesin LaCoO3" @default.
• W2990524491 doi "https://doi.org/10.1021/acsami.9b08406.s003" @default.
• W2990524491 hasPublicationYear "2019" @default.
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