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- W2990637355 abstract "Abstract Developing stable conductive materials with high conductivity for sodium ion (Na + ) batteries attracts ever‐increasing attention. In this work, MOF‐based solid Na + ‐conducting composites functionalized by ionic liquids (ILs) were explored through introducing five kinds of ILs and their corresponding sodium salts into the pores of MIL‐101‐SO 3 Na. The pore‐filling fraction of MIL‐101‐SO 3 Na was established and revealed as a key factor to enhance the ionic conductivity of the composites. Na‐salts could further improved the conductivity by increasing the number of conductive ions. Furthermore, all ILs and Na‐salts@MIL‐101‐SO 3 Na hybrid composites showed sharply enhanced ionic conductivity and displayed low activation energy. Particularly, as the pore‐filling faction elevating to 96.94 % with [Emim][BF 4 ] and NaBF 4 in the pores of MIL‐101‐SO 3 Na the ionic conductivity reached up to 1.32×10 −2 S cm −1 and stabilized within 30 days at 150 °C. This study on Na + ‐conduction in a MOF‐based system functionalized by ILs, providing guidance for exploring new solid ionic conducting materials." @default.
- W2990637355 created "2019-12-05" @default.
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- W2990637355 date "2019-12-20" @default.
- W2990637355 modified "2023-10-16" @default.
- W2990637355 title "Combining Ionic Liquids and Sodium Salts into Metal‐Organic Framework for High‐Performance Ionic Conduction" @default.
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- W2990637355 doi "https://doi.org/10.1002/celc.201901753" @default.
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