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• W2990640354 abstract "An alkynyl-protected gold nanocluster, Au22 (t BuC≡C)18 (1), has been synthesized and its structure has been determined by single-crystal X-ray diffraction. The molecular structure consists of a Au13 cuboctahedron kernel and three [Au3 (t BuC≡C)4 ] trimeric staples. The cluster 1 has strong luminescence in the solid state with a 15 % quantum yield, and it displays interesting thermochromic luminescence as revealed by temperature-dependent emission spectra. The enhanced room-temperature emission is characterized as thermally activated delayed fluorescence." @default.
• W2990640354 created "2019-12-05" @default.
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• W2990640354 date "2020-02-03" @default.
• W2990640354 modified "2023-10-15" @default.
• W2990640354 title "Structure Determination of Alkynyl‐Protected Gold Nanocluster Au ₂₂ ( ^t BuC≡C) ₁₈ and Its Thermochromic Luminescence" @default.
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• W2990640354 doi "https://doi.org/10.1002/anie.201912984" @default.
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• W2990640354 hasPublicationYear "2020" @default.
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