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• W2990936978 abstract "In this study, a novel spray drying-assisted self-assembly (SDAS) technology was proposed to prepare submicron elemental explosives with good morphology, uniform dispersion, and low sensitivity and spherical submicron RDX, HMX, and CL-20 particles without soft agglomeration were fabricated via such a method. Structural characterizations and thermal stability of the composites were systematically studied by scanning electron microscopy (SEM), X-ray diffraction (XRD), and differential scanning calorimeter (DSC). Moreover, safety performance was analyzed by qualitative testing of impact sensitivity and friction sensitivity. The XRD analysis demonstrated that HMX and CL-20 refined by SDAS maintained the crystal structure of β -HMX and ε -CL-20 before and after refinement, whereas the HMX crystal structure after spray recrystallization refinement was transformed from β -HMX to α -HMX. The DSC results indicated that the thermal decomposition peak temperature of the three particles refined by the SDAS technology had a minimum advancement, and the thermal stability of the particles was relatively superior. More importantly, the <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML id=M1><mml:msub><mml:mrow><mml:mi>H</mml:mi></mml:mrow><mml:mrow><mml:mn>50</mml:mn></mml:mrow></mml:msub></mml:math> of the RDX, HMX, and CL-20 refined by this novel method was increased to 48.3 cm, 44.6 cm, and 31.1 cm, and the probability of friction explosion was decreased to 62%, 62%, and 80%, respectively, thus significantly improving the safety performance as compared with the sample refined by spray recrystallization." @default.
• W2990936978 created "2019-12-05" @default.
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• W2990936978 date "2019-11-26" @default.
• W2990936978 modified "2023-10-16" @default.
• W2990936978 title "Fabrication and Characterization of Submicron Scale Spherical RDX, HMX, and CL-20 without Soft Agglomeration" @default.
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• W2990936978 doi "https://doi.org/10.1155/2019/7394762" @default.
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