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• W2991208178 abstract "CuZnSe2 (CZSe) is an important ternary semiconductor comprised of earth-abundant elements with a suitable bandgap for visible light absorption and structural/stoichiometric versatility that make it a promising candidate for photovoltaic applications. Here we report the controlled synthesis of the compound copper chalcogenide in nanocrystal form using a colloidal hot injection approach. Furthermore, we demonstrate control over the crystal phase to occur as either wurtzite (WZ) or zinc blende (ZB) as a function of the presence and absence of phosphine-based ligands. A major emission peak was observed at ∼1.7 eV using low-temperature photoluminescence (PL), ranging from 30 to 200 K. Additionally, we demonstrate the ability to extend this synthetic protocol to form a polytype structure comprised of a ZB core with a WZ shell." @default.
• W2991208178 created "2019-12-05" @default.
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• W2991208178 creator A5080239853 @default.
• W2991208178 creator A5090569594 @default.
• W2991208178 date "2019-11-25" @default.
• W2991208178 modified "2023-10-14" @default.
• W2991208178 title "Synthesis and Characterization of CuZnSe₂ Nanocrystals in Wurtzite, Zinc Blende, and Core–Shell Polytypes" @default.
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