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- W2991284752 abstract "Significance Contrary to our intuition, even a single-component substance may have more than 2 liquid states. The transition between them is called “liquid–liquid transition (LLT).” Recently, we have accumulated evidence for the presence of LLT. This transition may have a strong influence on crystallization, if it exists below the melting point of the crystal. Here we show that crystal nucleation rate can indeed be enhanced by many orders of magnitude near the spinodal point of LLT. This may be used not only for the control of crystalline morphology but also for searching LLT in a metastable state, which is hidden behind crystallization. Our finding also sheds light on how crystallization and other liquid-state transitions can be coupled." @default.
- W2991284752 created "2019-12-05" @default.
- W2991284752 creator A5005967783 @default.
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- W2991284752 date "2019-11-25" @default.
- W2991284752 modified "2023-10-17" @default.
- W2991284752 title "Drastic enhancement of crystal nucleation in a molecular liquid by its liquid–liquid transition" @default.
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- W2991284752 doi "https://doi.org/10.1073/pnas.1909660116" @default.
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