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- W2991424580 abstract "The reactions of boryl anion [(CH)2(NDipp)2]BLi (Dipp = 2,6-iPr2C6H3) (1) with a series of silicon halides and alkoxysilanes were investigated. Treatment of 1 with SiCl4 and PhSiCl3 afforded corresponding borylsilanes [(CH)2(NDipp)2]BSiCl3 (2) and [(CH)2(NDipp)2]BSiPhCl2 (3), respectively, in good yields. Reaction of HSiCl3 with 1 yielded a mixture of [(CH)2(NDipp)2]BSiHCl2 (4) and [(CH)2(NDipp)2]BH whereas the similar reaction with PhSiHCl2 yielded the borylsilane [(CH)2(NDipp)2]BSiPhHCl (5) as a sole product. In contrast, reaction of 1 with SiBr4 led to the reduction of SiBr4 with the formation of [(CH)2(NDipp)2]BBr and the expected substituted product [(CH)2(NDipp)2]BSiBr3 (6) was not formed. Reaction of alkoxysilane RSi(OMe)3 (R = H, Ph, Np, OMe) with 1 exclusively yielded the substituted product [(CH)2(NDipp)2]BSiR(OMe)2 (7a-d), which reacted with BBr3 to give the bromides [(CH)2(NDipp)2]BSiRBr2 (8a-c, R = H, Ph, Np) and [(CH)2(NDipp)2]BSiBr3 (6, R = OMe). These products have been characterized spectroscopically as well as X-ray single-crystal analysis in some cases." @default.
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- W2991424580 date "2020-01-01" @default.
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- W2991424580 title "Reaction of a boryl anion with silicon halides and alkoxysilanes: Synthesis of borylsilanes" @default.
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- W2991424580 doi "https://doi.org/10.1016/j.jorganchem.2019.121041" @default.
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