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- W2992135330 endingPage "10119" @default.
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- W2992135330 abstract "A highly diastereoselective desymmetrization of p-quinamines via regioselective ring opening of epoxides and aziridines under mild conditions has been developed. A chairlike six-membered transition state with minimized 1,3-diaxial interactions explains the relative stereoselectivity of the cyclization reaction. This transition-metal free [3 + 3] annulation reaction provides rapid access to fused bicyclic morpholines and piperazines with a tetrasubstituted carbon center in high yields. In addition, it also allows the synthesis of enantioenriched products by using easily accessible chiral nonracemic epoxides and aziridines." @default.
- W2992135330 created "2019-12-13" @default.
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- W2992135330 date "2019-12-05" @default.
- W2992135330 modified "2023-10-05" @default.
- W2992135330 title "Diastereoselective Desymmetrization of <i>p</i>-Quinamines through Regioselective Ring Opening of Epoxides and Aziridines" @default.
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- W2992135330 doi "https://doi.org/10.1021/acs.orglett.9b04110" @default.
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