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- W2992154654 abstract "Horse-chestnut ethanolic extract was tested as potential corrosion inhibitor of bronze in simulated acid rain. The extract was analysed by FTIR, GC–MS and HPLC-PDA, and its anti-corrosion behaviour studied using a multiscale electrochemical approach by polarization curves, EIS and scanning electrochemical microscopy, along with SEM-EDS. 94 % inhibition efficiency was attained by developing a surface physisorbed film. A novel methodology for kinetic evaluation of dynamic adsorption of inhibitive species on metal surface is proposed using SECM, achieving good agreement with results from conventional electrochemical techniques. Excellent adsorption-desorption kinetic constants (ka = 0.102 s−1 mol−1 L; kd = 3.33 × 10-5 s−1) were determined." @default.
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- W2992154654 date "2020-04-01" @default.
- W2992154654 modified "2023-10-16" @default.
- W2992154654 title "Multiscale electrochemical analysis of the corrosion control of bronze in simulated acid rain by horse-chestnut (Aesculus hippocastanum L.) extract as green inhibitor" @default.
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- W2992154654 doi "https://doi.org/10.1016/j.corsci.2019.108381" @default.
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