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- W2992725721 abstract "Abstract Electron localization in anion radicals of aromatic compounds built with two electrophores was studied using Vis, NIR, IR and ESR spectroscooy and electrochemistry. N,N′,-Bis (2,5-di-tert-butylphenyl)-2,3,6,7-anthracene-docarboximide anion radical has the odd electron mainly localized on the anthracene bridge. This contrasts with its diquinone analog, 1,4,8,11-pentacenetetrone, which has the odd electron localized on one quinone at a time. The anion radical of the tatrakis-(N-cyanoimine) derivative of 5,7,12,14-pentacenetetrone (3−) is delocalized. The solid state conductivity of the salts M+, 3− ranges from 10−4 S cm−1 for M=Bu4N to 0.4 S cm−1 for M=Na" @default.
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- W2992725721 date "1991-05-24" @default.
- W2992725721 modified "2023-09-23" @default.
- W2992725721 title "Mixed Valence in Conjugated Anion Radicals. Solution and Solid State Studies" @default.
- W2992725721 doi "https://doi.org/10.21236/ada236428" @default.
- W2992725721 hasPublicationYear "1991" @default.
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