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- W2992956095 abstract "Volumetric and acoustic properties of p-cymene with fluorobenzene, chlorobenzene and bromobenzene have been investigated using density, ( ρ ), and speed of sound, ( U ) measurements over the entire composition range at T= (303.15, 308.15 and 313.15) K. From the experimentally measured density, ( ρ ); Excess molar volumes, ( V ), infinite dilution partial molar volume, ( , i ) excess partial molar volume, ( , ) apparent molar volume, ( V, m,ϕ, 1 ), infinite dilution apparent molar volume, ( V , , ϕ, 1 ) with empirical parameters, S v , B v and limiting apparent molar expansibility, ( E ) have been calculated. Deviation in speed of sound ( U ), deviation in isentropic compressibility, ( k s ), deviation in acoustic impedance, ( z ), infinite dilution partial molar isentropic compressibility, ( , m, i ), excess partial molar isentropic compressibility, ( , i ), apparent molar isentropic compressibility, ( K s,m,ϕ,i ), infinite dilution apparent molar isentropic compressibility, ( K m,ϕ,1 ) with empirical parameters S k and B k and intermolecular free length (L f ) have been calculated using experimentally measured speed of sound, ( U ). To derive fitting coefficients, ( Ai ) with standard deviation, (σ), excess properties were fitted to the Redlich-Kister type polynomial equation. Various theoretical speed of sound and average deviations have been calculated using well established equation like Nomoto, ( U nmt ) Ideal Mixing Rule, ( U imr ) Junji, ( U junji ) and Jacobson’s Free Length Theory, ( U flt ). The variation of these properties with composition and temperature has been discussed in terms of molecular interaction on mixing and their interacting abilities have also been compared." @default.
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- W2992956095 date "2019-11-18" @default.
- W2992956095 modified "2023-09-26" @default.
- W2992956095 title "Study on volumetric and acoustic properties of binary mixtures of p-Cymene with fluorobenzene, chlorobenzene and bromobenzene at various temperatures" @default.
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