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- W2993065322 abstract "A systematic kinetic study on the oxidation of histidine by peroxomonosulphate (PMS) in acetic acidsodium acetate buffered medium (pH 3.6-4.8) and the catalytic effect of copper(II) was investigated. EPR spectral data ruled out the involvement of free radical intermediate. Formation of copper – histidine – PMS complex was established by cyclic voltammetric and UV –visible absorption studies. NMR studies confirmed that the product formed in this reaction was imidazole -4-acetaldehyde. A suitable mechanism was proposed." @default.
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- W2993065322 date "2015-01-01" @default.
- W2993065322 modified "2023-09-23" @default.
- W2993065322 title "Mechanistic Investigation of Copper (II) Catalysed Oxidative Deamination and Decarboxylation of Histidine by Peroxomonosulphate in Buffered Medium" @default.
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