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- W2993786799 abstract "The flavonol quercetin, its glycoside rutin, the flavanol catechin, the isoflavone daidzein and 5,6,4′-trihydroxyisoflavone can be oxidatively polymerized via a radical polyrecombination mechanism catalyzed by horseradish or soybean peroxidase in a mixture of phosphate buffer (pH 7) and 1,4-dioxane. The average molecular weights of the polymers were found to be in the range 4 000–12 000 g/mol. Daidzein derivatives with a methoxy (formononetin) or nitro group or a hydrogen atom at C-4′ could not be polymerized under these conditions. These results and molecular modeling studies suggest that polymerization preferentially occurs via the electron-rich ring B of the isoflavonoids. The polymers were characterized by means of FT-IR and UV spectroscopy, and their redox behavior was analyzed using cyclic voltammetry." @default.
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- W2993786799 date "2002-01-01" @default.
- W2993786799 modified "2023-10-17" @default.
- W2993786799 title "New Polymers from Natural Phenols Using Horseradish or Soybean Peroxidase" @default.
- W2993786799 doi "https://doi.org/10.1002/1616-5195(20020101)2:1<24::aid-mabi24>3.3.co;2-y" @default.
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