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- W2993798103 endingPage "10006" @default.
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- W2993798103 abstract "A highly diastereo- and enantioselective Ir-catalyzed hydrogenation of unfunctionalized 2,3-disubstituted quinolines, especially 3-alkyl-2-arylquinolines, has been realized. The success of this hydrogenation is ascribed to the use of a structurally fine-tuned chiral phosphine-phosphoramidite ligand with a (Sa)-3,3'-dimethyl H8-naphthyl moiety and (Rc)-1-phenylethylamine backbone. The hydrogenation displayed broad functional group tolerance, thus furnishing a wide range of optically active 2,3-disubstituted tetrahydroquinolines in up to 96% ee and with perfect cis-diastereoselectivity." @default.
- W2993798103 created "2019-12-13" @default.
- W2993798103 creator A5072111456 @default.
- W2993798103 date "2019-12-05" @default.
- W2993798103 modified "2023-10-14" @default.
- W2993798103 title "Highly Diastereo- and Enantioselective Ir-Catalyzed Hydrogenation of 2,3-Disubstituted Quinolines with Structurally Fine-Tuned Phosphine–Phosphoramidite Ligands" @default.
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- W2993798103 doi "https://doi.org/10.1021/acs.orglett.9b03925" @default.
- W2993798103 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31802677" @default.
- W2993798103 hasPublicationYear "2019" @default.
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