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- W299392987 abstract "The infrared and Raman spectra [10–3100 cm−1] have been recorded for aqueous solutions and polycrystalline samples of Na4P2S6 · 6H2O as well as for several lamellar MPS3 (or M2P2S6) compounds with M = Fe, Co, Ni, In23 and their intercalates with cobalticenium cations. A complete assignment of the observed spectra is proposed and a normal coordinate analysis of the [P2S4−6] anion is carried out; this allows proposal of a new assignment, for the spectra of the layered MPS3 host systems which is slightly modified with respect to prior work. A detailed analysis of the infrared and far-infrared spectra is also reported for the intercalates with [Co(η5-C5H5)+2] cations. From these results, it is concluded that the mechanism of the electronic transfer during the intercalation process depends on the nature of the metal: when M = Co or Ni the main reduction site is the PP bond, while when M = Fe (and perhaps also Mn) the reduction involves mainly the metal ion itself." @default.
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- W299392987 date "1983-09-01" @default.
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- W299392987 title "Vibrational study of the [P2S4−6] anion, of some MPS3 layered compounds (M = ), and of their intercalates with [Co(η5-C5H5)+2] cations" @default.
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- W299392987 doi "https://doi.org/10.1016/0022-4596(83)90107-x" @default.
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