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• W2994091680 abstract "Abstract This work investigated the kinetics of formic acid (FA) disproportionation using an Ir complex immobilized on bipyridine‐periodic mesoporous organosilica (BPy‐PMO). The selectivity for methanol (MeOH) is increased using this catalyst compared to conventional homogeneous Ir complexes. This enhanced selectivity is attributed to the retention of H 2 and CO 2 generated by the competing FA dehydrogenation in PMO mesochannels having a high aspect ratio. However, no direct evidence for this process was previously obtained. The present work clarified the unique catalysis mechanism associated with a PMO catalyst exhibiting higher MeOH selectivity based on a hypothesis that the generation of MeOH via FA hydrogenation is promoted by the confinement of H 2 in the PMO pores. The results obtained from the present kinetics study and data regarding H 2 diffusion in the PMO pores strongly support this hypothesis." @default.
• W2994091680 created "2019-12-13" @default.
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• W2994091680 date "2019-12-23" @default.
• W2994091680 modified "2023-09-27" @default.
• W2994091680 title "Mechanism of Formic Acid Disproportionation Catalyzed by an Iridium Complex Immobilized on Bipyridine‐Periodic Mesoporous Organosilica: A Case Study Based on Kinetics Analysis" @default.
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• W2994091680 doi "https://doi.org/10.1002/ajoc.201900692" @default.
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