FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2994246360> ?p ?o ?g. }

• W2994246360 endingPage "16857" @default.
• W2994246360 startingPage "16849" @default.
• W2994246360 abstract "An exploration of secondary coordination sphere (SCS) functional groups is presented with a focus on proton transport to a metal hydride active site for H2 formation and transport of CO2 so that formate can be obtained. In MeCN–H2O, pKa(AH) and steric bulk of the SCS groups are discussed along with their influence on each step in the mechanism for CO2 to formate catalysis and along with the influence of the proton source, which is MeCN–H2O or (MeCN)2H2O in MeCN–H2O (95:5) under N2 atmosphere. Under CO2, carbonic acid is also available. Catalysts containing various SCS groups were synthesized from [Fe4N(CO)12]− and have the form [Fe4N(CO)11L]− where L is Ph2P-SCS. Hydride formation rates are distinct under N2 versus CO2, and that variation is dependent on the size of the SCS group. Under CO2, larger SCS groups inhibit access of the MeCN–H2O adducts to the active site and formate formation is observed, whereas smaller SCS groups allow transport of these adducts. This is best illustrated by catalysts containing the small SCS group pyridyl and the large SCS group N,N-dimethylaniline which both have the same pKa(AH) value. The smaller pyridyl group promotes selective H2 evolution, whereas larger N,N-dimethylaniline supports selective formate formation by slowing the transport of large MeCN–H2O adducts, allowing hydride transfer to the smaller substrate CO2." @default.
• W2994246360 created "2019-12-13" @default.
• W2994246360 creator A5016374846 @default.
• W2994246360 creator A5074504010 @default.
• W2994246360 date "2019-12-05" @default.
• W2994246360 modified "2023-10-18" @default.
• W2994246360 title "Secondary Coordination Sphere Design to Modify Transport of Protons and CO₂" @default.
• W2994246360 cites W115304618 @default.
• W2994246360 cites W1963825575 @default.
• W2994246360 cites W1966070623 @default.
• W2994246360 cites W1971774443 @default.
• W2994246360 cites W1976002844 @default.
• W2994246360 cites W1977429025 @default.
• W2994246360 cites W1981281054 @default.
• W2994246360 cites W1982671514 @default.
• W2994246360 cites W1983841203 @default.
• W2994246360 cites W1987832365 @default.
• W2994246360 cites W1991967257 @default.
• W2994246360 cites W1999855579 @default.
• W2994246360 cites W2006276073 @default.
• W2994246360 cites W2008686504 @default.
• W2994246360 cites W2012191902 @default.
• W2994246360 cites W2019066123 @default.
• W2994246360 cites W2024778201 @default.
• W2994246360 cites W2027240076 @default.
• W2994246360 cites W2037409496 @default.
• W2994246360 cites W2038312285 @default.
• W2994246360 cites W2044830011 @default.
• W2994246360 cites W2054406704 @default.
• W2994246360 cites W2059971091 @default.
• W2994246360 cites W2060874745 @default.
• W2994246360 cites W2065818181 @default.
• W2994246360 cites W2067468321 @default.
• W2994246360 cites W2070150234 @default.
• W2994246360 cites W2071551353 @default.
• W2994246360 cites W2081923307 @default.
• W2994246360 cites W2083878738 @default.
• W2994246360 cites W2116255848 @default.
• W2994246360 cites W2139078293 @default.
• W2994246360 cites W2162867724 @default.
• W2994246360 cites W2196405748 @default.
• W2994246360 cites W2227954947 @default.
• W2994246360 cites W2320103652 @default.
• W2994246360 cites W2321558777 @default.
• W2994246360 cites W2327780497 @default.
• W2994246360 cites W2330098546 @default.
• W2994246360 cites W2332259249 @default.
• W2994246360 cites W2332448579 @default.
• W2994246360 cites W2333481394 @default.
• W2994246360 cites W2340647107 @default.
• W2994246360 cites W2438457320 @default.
• W2994246360 cites W2477754403 @default.
• W2994246360 cites W2482236566 @default.
• W2994246360 cites W2541509409 @default.
• W2994246360 cites W2587896894 @default.
• W2994246360 cites W2604933674 @default.
• W2994246360 cites W2604999710 @default.
• W2994246360 cites W2608893679 @default.
• W2994246360 cites W2747030391 @default.
• W2994246360 cites W2766349903 @default.
• W2994246360 cites W2787936482 @default.
• W2994246360 cites W2788086056 @default.
• W2994246360 cites W2792809770 @default.
• W2994246360 cites W2793794701 @default.
• W2994246360 cites W2804094883 @default.
• W2994246360 cites W2808205168 @default.
• W2994246360 cites W2811512713 @default.
• W2994246360 cites W2835456725 @default.
• W2994246360 cites W2884812270 @default.
• W2994246360 cites W2891145257 @default.
• W2994246360 cites W2891819997 @default.
• W2994246360 cites W2898377143 @default.
• W2994246360 cites W2901028134 @default.
• W2994246360 cites W2901779357 @default.
• W2994246360 cites W2908722217 @default.
• W2994246360 cites W2916737079 @default.
• W2994246360 cites W2930586923 @default.
• W2994246360 cites W2943173984 @default.
• W2994246360 cites W3005352396 @default.
• W2994246360 cites W4253339442 @default.
• W2994246360 doi "https://doi.org/10.1021/acs.inorgchem.9b03102" @default.
• W2994246360 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31802660" @default.
• W2994246360 hasPublicationYear "2019" @default.
• W2994246360 type Work @default.
• W2994246360 sameAs 2994246360 @default.
• W2994246360 citedByCount "17" @default.
• W2994246360 countsByYear W29942463602020 @default.
• W2994246360 countsByYear W29942463602021 @default.
• W2994246360 countsByYear W29942463602022 @default.
• W2994246360 countsByYear W29942463602023 @default.
• W2994246360 crossrefType "journal-article" @default.
• W2994246360 hasAuthorship W2994246360A5016374846 @default.
• W2994246360 hasAuthorship W2994246360A5074504010 @default.
• W2994246360 hasBestOaLocation W29942463603 @default.
• W2994246360 hasConcept C108204754 @default.
• W2994246360 hasConcept C11111787 @default.
• W2994246360 hasConcept C121332964 @default.
• W2994246360 hasConcept C155647269 @default.

• next