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- W2994290717 endingPage "108101" @default.
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- W2994290717 abstract "Abstract Based on different benzenecarboxylic acids (H3BTC = 1,3,5-benzenetricarboxylic acid; H4BTEC = 1,2,4,5-benzenetetracarboxylic acid; m-H3BTC = 1,2,4-benzenetricarboxylic acid) and viologen cations (BV2+ = 1,1′-bis(butyl)-4,4′-bipyridinium dication; AV2+ = 1,1′-bis(amyl)-4,4′-bipyridinium dication; HV2+ = 1,1′-bis(hexyl)-4,4′-bipyridinium dication), five novel supramolecular assemblies (BV)(H2BTC)2(H3BTC)2 (1), [(BV)0.5(H3BTEC)]·H2O (2), (BV)0.5(m-H2BTC) (3), (AV)0.5(m-H2BTC) (4), (HV)0.5(m-H2BTC) (5) have been prepared. The electron-deficient viologen groups and the electron-donating benzenecarboxylate units are hydrogen-bonded to form the donor-acceptor (D–A) system. Under light illumination, photoactivated electrons can be transferred from the donor to the acceptor units in compounds 2–5. Their different photoactive properties can be attributed to the alkyl groups introduced, packing and valence of the functional D–A moieties." @default.
- W2994290717 created "2019-12-13" @default.
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- W2994290717 date "2020-03-01" @default.
- W2994290717 modified "2023-09-27" @default.
- W2994290717 title "Photoresponsive characteristics of five D–A supramolecular assemblies derived from benzenecarboxylate donors and viologen acceptors" @default.
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- W2994290717 doi "https://doi.org/10.1016/j.dyepig.2019.108101" @default.
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