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- W2994729151 abstract "Novel electrolytes composed of chondroitin sulfate A (CSA) and citric acid (CA) have been prepared using a clean, safe, and fast route. These electrolytes exhibit different physical-chemical properties, depending on the amount of CA. For X > 82.3%, where X is the mass ratio, in %, of CA/(CA + CSA), whitish polycrystalline powders result. Lower amounts of CA leads to the production of translucent, amorphous films, sticky for X = 75.6 and 82.0, brittle for X < 43.6 and crack-free, self-standing for 43.6 < X < 75.6%. The results obtained provide evidence that, at low pH, strong hydrogen bonding interactions take place between the anionic sulfonic and carboxylic groups of CSA and CA. CA exerts a key role, acting as a cross-linker and proton source, while simultaneously influencing sample morphology. At room temperature the highest ionic conductivity is achieved at X = 60.8%. A significant enhancement of the ionic conductivity of this sample occurs with the increase of relative humidity (RH) (from 3.1 × 10−7 to 3.7 × 10−2 S cm−1 30% for RH = 30 and ~100%, respectively)." @default.
- W2994729151 created "2019-12-26" @default.
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- W2994729151 date "2020-02-01" @default.
- W2994729151 modified "2023-09-26" @default.
- W2994729151 title "Proton conducting electrolytes composed of chondroitin sulfate polysaccharide and citric acid" @default.
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- W2994729151 doi "https://doi.org/10.1016/j.eurpolymj.2019.109453" @default.
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