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- W2994742009 abstract "Abstract A pair of enantiomers of three‐dimensional (3D) chiral coordination polymers (CCPs) were successfully constructed by using achiral components 4,2′:6′,4′′‐terpyridyl precursors and Cu 2+ through spontaneous resolution ( 1 a ). By utilising feeding controlled chiral‐templated induction and chiral auxiliary behaviour of optically pure camphor sulfonate (CSA), the enantioenriched ( 1 b‐P and 1 b‐M ) and CSA captured ( 1 c‐P and 1 c‐M ) CCPs were successfully synthesised, respectively. The chiral information of the corresponding products was confirmed by X‐ray single crystal diffraction and solid‐state CD spectra. Meanwhile, the formation processes of 1 b‐P and 1 b‐M were monitored through solution CD spectra, UV/Vis spectra and ESI‐TOF MS. Based on these results, a reasonable chiral‐templated induction mechanism of forming 1 b‐P and 1 b‐M was proposed." @default.
- W2994742009 created "2019-12-26" @default.
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- W2994742009 date "2020-01-28" @default.
- W2994742009 modified "2023-10-17" @default.
- W2994742009 title "Chiral 3D Coordination Polymers Consisting of Achiral Terpyridyl Precursors: from Spontaneous Resolution to Enantioenriched Induction" @default.
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- W2994742009 doi "https://doi.org/10.1002/chem.201905091" @default.
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