FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2995078176> ?p ?o ?g. }

• W2995078176 endingPage "115170" @default.
• W2995078176 startingPage "115170" @default.
• W2995078176 abstract "The cubic phase of lithium lanthanum zirconium oxide (LLZO) is a solid electrolyte based on the garnet crystal structure which has shown promise in enabling batteries with significantly higher energy density compared to lithium-ion. Owing to its stability against lithium, LLZO is compatible with metallic lithium electrodes that, when paired with state-of-the-art cathodes, can achieve >1000 Wh/l. The preferred cubic LLZO phase is stabilized at room temperature by doping LLZO, which results in the formation of lithium vacancies (VLi′) that can achieve ionic conductivities in the 1 mS/cm range. While much attention has been paid to optimizing VLi′, discrepancies in lanthanum to zirconium (La:Zr) ratios provide an indication of the existence of vacancies at one or both of these sites. As La is the largest cation present, La vacancies should show the most dramatic effects on lattice parameter, which should affect lithium-ion transport within the LLZO sublattice. In turn, changes in lithium-ion site occupancy and solvation should affect activation energy and conductivity. However, the effects of the sub stoichiometric use of La on the crystal structure of LLZO have yet to be characterized. In this work, La content is varied in the LLZO structure Li6.5La2+xZr1.5Ta0.5O12 from x = 0 to x = 1.2. X-ray diffraction, SEM imaging, Raman Spectroscopy, electrochemical impedance measurements, and DC cycling were performed in order to correlate the effect of La deficiency on crystal structure and electrochemical properties of LLZO. Vacancy and decomposition mechanism are proposed. A linear increase in lattice parameter is observed over the range of La content measured. An increase in conductivity and CCD are also observed ranging from 0.649 mS/cm and 0.5 mA/cm2 at x = 0.2 to 0.789mS/cm and 0.80 mA/cm2 at x = 1.0." @default.
• W2995078176 created "2019-12-26" @default.
• W2995078176 creator A5075933059 @default.
• W2995078176 creator A5081987488 @default.
• W2995078176 date "2020-02-01" @default.
• W2995078176 modified "2023-09-27" @default.
• W2995078176 title "The effect of lanthanoid defects on anionic solvation of Li in Li6.5La2+xZr1.5Ta0.5O12 from x = 0 to x = 1.2 garnet" @default.
• W2995078176 cites W1752951405 @default.
• W2995078176 cites W1949231392 @default.
• W2995078176 cites W1988158958 @default.
• W2995078176 cites W1988952412 @default.
• W2995078176 cites W2008474857 @default.
• W2995078176 cites W2008845571 @default.
• W2995078176 cites W2009979272 @default.
• W2995078176 cites W2016624453 @default.
• W2995078176 cites W2019368249 @default.
• W2995078176 cites W2030524341 @default.
• W2995078176 cites W2040484663 @default.
• W2995078176 cites W2059179897 @default.
• W2995078176 cites W2068157181 @default.
• W2995078176 cites W2069691371 @default.
• W2995078176 cites W2086855351 @default.
• W2995078176 cites W2092864249 @default.
• W2995078176 cites W2143795526 @default.
• W2995078176 cites W2148558281 @default.
• W2995078176 cites W2262181592 @default.
• W2995078176 cites W2267276271 @default.
• W2995078176 cites W2289255670 @default.
• W2995078176 cites W2310846280 @default.
• W2995078176 cites W2406527223 @default.
• W2995078176 cites W2494408189 @default.
• W2995078176 cites W2560348663 @default.
• W2995078176 cites W2583015190 @default.
• W2995078176 cites W2743348143 @default.
• W2995078176 cites W2750682527 @default.
• W2995078176 cites W2762234774 @default.
• W2995078176 cites W2774455884 @default.
• W2995078176 cites W2791294928 @default.
• W2995078176 cites W2798190447 @default.
• W2995078176 cites W2910412185 @default.
• W2995078176 cites W2946353331 @default.
• W2995078176 doi "https://doi.org/10.1016/j.ssi.2019.115170" @default.
• W2995078176 hasPublicationYear "2020" @default.
• W2995078176 type Work @default.
• W2995078176 sameAs 2995078176 @default.
• W2995078176 citedByCount "8" @default.
• W2995078176 countsByYear W29950781762021 @default.
• W2995078176 countsByYear W29950781762022 @default.
• W2995078176 countsByYear W29950781762023 @default.
• W2995078176 crossrefType "journal-article" @default.
• W2995078176 hasAuthorship W2995078176A5075933059 @default.
• W2995078176 hasAuthorship W2995078176A5081987488 @default.
• W2995078176 hasBestOaLocation W29950781761 @default.
• W2995078176 hasConcept C113196181 @default.
• W2995078176 hasConcept C114221277 @default.
• W2995078176 hasConcept C115624301 @default.
• W2995078176 hasConcept C134018914 @default.
• W2995078176 hasConcept C138679309 @default.
• W2995078176 hasConcept C147789679 @default.
• W2995078176 hasConcept C17525397 @default.
• W2995078176 hasConcept C179104552 @default.
• W2995078176 hasConcept C185592680 @default.
• W2995078176 hasConcept C191897082 @default.
• W2995078176 hasConcept C192562407 @default.
• W2995078176 hasConcept C2778541603 @default.
• W2995078176 hasConcept C43617362 @default.
• W2995078176 hasConcept C52859227 @default.
• W2995078176 hasConcept C534791751 @default.
• W2995078176 hasConcept C555894677 @default.
• W2995078176 hasConcept C68801617 @default.
• W2995078176 hasConcept C7040849 @default.
• W2995078176 hasConcept C71924100 @default.
• W2995078176 hasConcept C8010536 @default.
• W2995078176 hasConceptScore W2995078176C113196181 @default.
• W2995078176 hasConceptScore W2995078176C114221277 @default.
• W2995078176 hasConceptScore W2995078176C115624301 @default.
• W2995078176 hasConceptScore W2995078176C134018914 @default.
• W2995078176 hasConceptScore W2995078176C138679309 @default.
• W2995078176 hasConceptScore W2995078176C147789679 @default.
• W2995078176 hasConceptScore W2995078176C17525397 @default.
• W2995078176 hasConceptScore W2995078176C179104552 @default.
• W2995078176 hasConceptScore W2995078176C185592680 @default.
• W2995078176 hasConceptScore W2995078176C191897082 @default.
• W2995078176 hasConceptScore W2995078176C192562407 @default.
• W2995078176 hasConceptScore W2995078176C2778541603 @default.
• W2995078176 hasConceptScore W2995078176C43617362 @default.
• W2995078176 hasConceptScore W2995078176C52859227 @default.
• W2995078176 hasConceptScore W2995078176C534791751 @default.
• W2995078176 hasConceptScore W2995078176C555894677 @default.
• W2995078176 hasConceptScore W2995078176C68801617 @default.
• W2995078176 hasConceptScore W2995078176C7040849 @default.
• W2995078176 hasConceptScore W2995078176C71924100 @default.
• W2995078176 hasConceptScore W2995078176C8010536 @default.
• W2995078176 hasFunder F4320306084 @default.
• W2995078176 hasLocation W29950781761 @default.
• W2995078176 hasLocation W29950781762 @default.
• W2995078176 hasOpenAccess W2995078176 @default.
• W2995078176 hasPrimaryLocation W29950781761 @default.

• next