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• W2995247953 abstract "The synthesis of cycloarenes in solution is challenging because of their low solubility and the often hindered cyclodehydrogenation reaction of their nonplanar precursors. Using an alternative on-surface synthesis protocol, we achieved an unprecedented double-stranded hexagonal cycloarene containing 108 sp2 carbon atoms. Its synthesis is based on hierarchical Ullmann coupling and cyclodehydrogenation of a specially designed precursor on a Au(111) surface. The structure and other properties of the cycloarene are investigated by scanning tunneling microscopy/spectroscopy, atomic force microscopy, and density functional theory calculations." @default.
• W2995247953 created "2019-12-26" @default.
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• W2995247953 date "2019-12-16" @default.
• W2995247953 modified "2023-10-17" @default.
• W2995247953 title "On-Surface Synthesis and Characterization of a Cycloarene: C108 Graphene Ring" @default.
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• W2995247953 doi "https://doi.org/10.1021/jacs.9b10151" @default.
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