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- W2995584772 abstract "Orientation relationships (ORs) can form during solidification by a variety of mechanisms that are often difficult to distinguish after solidification. Here we study three ORs formed by the nucleation of Al 3 Ti on TiB 2 , and by the pushing and engulfment of TiB 2 by growing Al 3 Ti facets in hyperperitectic Al-rich melts. The nucleation OR is identified by growing a relatively large TiB 2 crystal, solidifying multiple small Al 3 Ti crystals on one (0001) facet of TiB 2 , and measuring the resulting OR by electron backscatter diffraction (EBSD). Pushing and engulfment ORs are investigated by statistical analysis of EBSD measurements, density functional theory (DFT) calculations of interface energies, and imaging of cross-sections of TiB 2 particles being pushed and engulfed by Al 3 Ti facets. It is shown that the lowest energy OR is formed by nucleation as well as by pushing/engulfment. The higher energy ORs, formed by pushing and engulfment, correspond to local interfacial energy minima and can be explained by rotation of TiB 2 particles on Al 3 Ti facets during pushing." @default.
- W2995584772 created "2019-12-26" @default.
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- W2995584772 date "2020-03-01" @default.
- W2995584772 modified "2023-10-06" @default.
- W2995584772 title "Solidification orientation relationships between Al3Ti and TiB2" @default.
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- W2995584772 doi "https://doi.org/10.1016/j.actamat.2019.12.013" @default.
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