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- W2995590718 abstract "We report an experimental observation of Rashba splitting in methylammonium lead iodide (MAPbI3). Because of a large spin–orbit coupling parameter in the noncentrosymmetric material, both of the bands were predicted to split having two different spin-textures leading to two different Z-components of total angular momentum (JZ). We use spin-polarized scanning tunneling spectroscopy to probe only one-type of JZ-matched bands throughout the film; dI/dV spectra recorded at many different points of a film however allowed us to spot both the Rashba split-levels and also deliberate on their spin-textures. We observe that the bands split in such a manner that the conduction and valence bands closer to the Fermi energy have the same type of spin-textures (a spin-allowed transition model). Still a low recombination rate of photogenerated carriers in MAPbI3 has been analyzed by considering Wannier-type excitons, a molecular nature of spin-domains from dI/dV images, and therefore a spin-forbidden nature of interdomain transition." @default.
- W2995590718 created "2019-12-26" @default.
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- W2995590718 date "2019-12-16" @default.
- W2995590718 modified "2023-10-18" @default.
- W2995590718 title "Rashba Band Splitting in CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub>: An Insight from Spin-Polarized Scanning Tunneling Spectroscopy" @default.
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- W2995590718 doi "https://doi.org/10.1021/acs.nanolett.9b03800" @default.
- W2995590718 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31841346" @default.
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