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• W2996207813 abstract "Abstract The room temperature reaction of Hg(NO 3 ) 2 · H 2 O, cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane) and K 8 {Nb 6 O 19 } · 16 H 2 O in a mixture of H 2 O and DMSO led to crystallization of the novel compound {[Hg(cyclam)] 6 Nb 6 O 19 }(NO 3 ) 4 · 14 H 2 O, which is the first mercury containing polyoxoniobate. The structure consists of a {Nb 6 O 19 } 8− cluster core which is expanded by six [Hg(cyclam)] 2+ complexes via Hg– μ 2 -O–Nb bond formation. The title compound contains a positively charged polyoxoniobate cluster. The crystal water molecules form small aggregates by O–H · · · O hydrogen bonding which are joined into larger aggregates by N–O · · · H–O hydrogen bonding integrating the nitrate anions." @default.
• W2996207813 created "2019-12-26" @default.
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• W2996207813 date "2019-12-10" @default.
• W2996207813 modified "2023-10-17" @default.
• W2996207813 title "A hexaniobate expanded by six [Hg(cyclam)]²⁺ complexes via Hg–O bonds yields a positively charged polyoxoniobate cluster" @default.
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• W2996207813 doi "https://doi.org/10.1515/znb-2019-0171" @default.
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