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- W2996228051 endingPage "113748" @default.
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- W2996228051 abstract "Abstract The novel CoCu metal-organic framework (CoCu-MOF) precursor and CoCu-MOF/polyaniline (CoCu-MOF/PANI) electrode materials were synthesized by hydrothermal method and in situ polymerization, respectively. The as-synthesized CoCu-MOF/PANI and corresponding composite were first tested for their electrocatalytic performance towards glycerol oxidation in KOH solution and then the selection and optimization were further carried out for the CoCu-MOF/PANI composite. The preferred material was subjected to a group of electrochemical performance tests such as cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), Tafel, and chronoamperometry. The results show that among the various electrode materials, the as-synthesized CoCu-MOF1/PANI1 hybrid exhibits enhanced electrocatalytic activity at the scanning speed of 100 mV s−1. EIS test manifests that the CoCu-MOF1/PANI1 has the lower impedance. Tafel test reveals that CoCu-MOF1/PANI1 is beneficial to increase the oxidation rate of glycerol. Chronoamperometry and CO stripping declare CoCu-MOF1/PANI1 has better stability and CO anti-poisoning relative to commercial Pt/C (20 wt%)-SA. The enhancement of electrochemical properties, stability and CO resistance is ascribed to the synergetic effect of CoCu-MOF and PANI substrate on the oxidation of glycerol." @default.
- W2996228051 created "2019-12-26" @default.
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- W2996228051 date "2020-01-01" @default.
- W2996228051 modified "2023-09-29" @default.
- W2996228051 title "Enhanced electrocatalytic performance of CoCu-MOF/polyaniline for glycerol oxidation" @default.
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- W2996228051 doi "https://doi.org/10.1016/j.jelechem.2019.113748" @default.
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