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• W2996359457 abstract "The cobalt-catalysed synthesis of four-membered carbocyclic ring systems from two alkene subunits in an intramolecular cycloaddition as well as in the intermolecular [2+2] cycloaddition of a strained alkene and an alkyne is an emerging field in organic synthesis. On the other hand, the [2+2] cycloaddition of two alkynes by a stoichiometric CpCo-fragment generates unique organometallic products with formally anti-aromatic cyclobutadiene ligands. Also, regioselective neutral Diels–Alder-type reactions of alkynes with 1,3-dienes can be catalysed with low-valent cobalt catalysts for the synthesis of various dihydroaromatic products that can be converted into arenes and several other interesting products and their applications in material sciences are outlined. Cobalt catalysis also allows cycloaddition reactions to form larger ring systems by [5+2] and [6+2] cycloadditions, and recent advances in the synthesis of [4.2.1] and [4.2.2] bicyclic unsaturated carbocycles are compiled." @default.
• W2996359457 created "2019-12-26" @default.
• W2996359457 creator A5059791913 @default.
• W2996359457 date "2019-12-20" @default.
• W2996359457 modified "2023-09-26" @default.
• W2996359457 title "Cobalt‐Catalysed Cycloaddition Reactions" @default.
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• W2996359457 doi "https://doi.org/10.1002/9783527814855.ch7" @default.
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