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- W2996435331 abstract "Compared with homopolymers, the copolymers exhibit improved properties, providing a broad application prospect. Herein, we report the visible-light-induced living/controlled radical copolymerization of acrylates or acrylamides and 1-octene mediated by organocobalt complexes at ambient temperature, giving copolymers with well-predictable molecular weights from 4400 to 27200 and low polydispersities in the range 1.17–1.28. The acrylic monomer reactivity ratio was calculated by monomer conversion and molar fraction of 1-octene without a complex fitting process. The electron-withdrawing groups on acrylic monomers resulted in low reactivity ratio down to 1.1 along with high molar fraction of 1-octene up to 34%, while electron-donating group led to increased reactivity ratio as 43 with a declined molar fraction of 1-octene as 3%. For the first time, a linear relationship between the logarithm of the reactivity ratio and the atomic charge of the propagating radical was observed, which affords a potential quantitative model to evaluate the electronic effect in other copolymerization systems." @default.
- W2996435331 created "2019-12-26" @default.
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- W2996435331 creator A5089786751 @default.
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- W2996435331 date "2019-12-19" @default.
- W2996435331 modified "2023-10-17" @default.
- W2996435331 title "Visible-Light-Induced Living/Controlled Radical Copolymerization of 1-Octene and Acrylic Monomers Mediated by Organocobalt Complexes" @default.
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- W2996435331 doi "https://doi.org/10.1021/acs.macromol.9b02066" @default.
- W2996435331 hasPublicationYear "2019" @default.
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