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- W2996509711 abstract "With the growing demand for high energy and high power density rechargeable lithium-ion batteries, increasing research is focused on improving the output voltage of these batteries. Herein, a series of pyrrolidinium and piperidinium cations with various N-substituents (including cyanomethyl, benzyl, butyl, hexyl, and octyl groups) were synthesized and investigated with respect to their electrochemical stability under high voltages. The influence of substitutions at the N-position of pyrrolidinium and piperidinium cations on their high-voltage resistance was studied by both theoretical and experimental approaches. The voltage resistance was enhanced as the electron-donating ability of the substitutes increased. Furthermore, 1-hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide ([C6Py][TFSI]) exhibited the highest decomposition voltage at approximately 5.12 V and showed promising potential in a lithium-ion battery." @default.
- W2996509711 created "2019-12-26" @default.
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- W2996509711 date "2019-12-10" @default.
- W2996509711 modified "2023-10-14" @default.
- W2996509711 title "High-Voltage Resistant Ionic Liquids for Lithium-Ion Batteries" @default.
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- W2996509711 doi "https://doi.org/10.1021/acsami.9b16786" @default.
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