FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2996567573> ?p ?o ?g. }

• W2996567573 endingPage "5642" @default.
• W2996567573 startingPage "5637" @default.
• W2996567573 abstract "Three unprecedented helical nanographenes (1, 2, and 3) containing an azulene unit are synthesized. The resultant helical structures are unambiguously confirmed by X-ray crystallographic analysis. The embedded azulene unit in 2 possesses a record-high twisting degree (16.1°) as a result of the contiguous steric repulsion at the helical inner rim. Structural analysis in combination with theoretical calculations reveals that these helical nanographenes manifest a global aromatic structure, while the inner azulene unit exhibits weak antiaromatic character. Furthermore, UV/Vis-spectral measurements reveal that superhelicenes 2 and 3 possess narrow energy gaps (2: 1.88 eV; 3: 2.03 eV), as corroborated by cyclic voltammetry and supported by density functional theory (DFT) calculations. The stable oxidized and reduced states of 2 and 3 are characterized by in-situ EPR/Vis-NIR spectroelectrochemistry. Our study provides a novel synthetic strategy for helical nanographenes containing azulene units as well as their associated structures and physical properties." @default.
• W2996567573 created "2019-12-26" @default.
• W2996567573 creator A5015297626 @default.
• W2996567573 creator A5026825791 @default.
• W2996567573 creator A5037641879 @default.
• W2996567573 creator A5043815724 @default.
• W2996567573 creator A5045885141 @default.
• W2996567573 creator A5047441212 @default.
• W2996567573 creator A5063351719 @default.
• W2996567573 creator A5073029911 @default.
• W2996567573 creator A5089322497 @default.
• W2996567573 creator A5090537271 @default.
• W2996567573 date "2020-02-03" @default.
• W2996567573 modified "2023-10-14" @default.
• W2996567573 title "Helical Nanographenes Containing an Azulene Unit: Synthesis, Crystal Structures, and Properties" @default.
• W2996567573 cites W1959464420 @default.
• W2996567573 cites W1975110717 @default.
• W2996567573 cites W2025658931 @default.
• W2996567573 cites W2066332565 @default.
• W2996567573 cites W2085291511 @default.
• W2996567573 cites W2128475062 @default.
• W2996567573 cites W2144770641 @default.
• W2996567573 cites W2156739932 @default.
• W2996567573 cites W2326772498 @default.
• W2996567573 cites W2330048111 @default.
• W2996567573 cites W2331886834 @default.
• W2996567573 cites W2333827620 @default.
• W2996567573 cites W2403028568 @default.
• W2996567573 cites W2495576215 @default.
• W2996567573 cites W2542980021 @default.
• W2996567573 cites W2549871537 @default.
• W2996567573 cites W2587968915 @default.
• W2996567573 cites W2602721287 @default.
• W2996567573 cites W2789831717 @default.
• W2996567573 cites W2792969961 @default.
• W2996567573 cites W2802338157 @default.
• W2996567573 cites W2888341288 @default.
• W2996567573 cites W2897555854 @default.
• W2996567573 cites W2901532705 @default.
• W2996567573 cites W2901549368 @default.
• W2996567573 cites W2903434215 @default.
• W2996567573 cites W2913155779 @default.
• W2996567573 cites W2916945752 @default.
• W2996567573 cites W2947491189 @default.
• W2996567573 cites W2959084130 @default.
• W2996567573 cites W2976744007 @default.
• W2996567573 cites W2996567573 @default.
• W2996567573 cites W4214689754 @default.
• W2996567573 cites W4242548888 @default.
• W2996567573 cites W4252157749 @default.
• W2996567573 cites W4253043518 @default.
• W2996567573 cites W4376849637 @default.
• W2996567573 doi "https://doi.org/10.1002/anie.201914716" @default.
• W2996567573 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7155134" @default.
• W2996567573 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31867754" @default.
• W2996567573 hasPublicationYear "2020" @default.
• W2996567573 type Work @default.
• W2996567573 sameAs 2996567573 @default.
• W2996567573 citedByCount "114" @default.
• W2996567573 countsByYear W29965675732020 @default.
• W2996567573 countsByYear W29965675732021 @default.
• W2996567573 countsByYear W29965675732022 @default.
• W2996567573 countsByYear W29965675732023 @default.
• W2996567573 crossrefType "journal-article" @default.
• W2996567573 hasAuthorship W2996567573A5015297626 @default.
• W2996567573 hasAuthorship W2996567573A5026825791 @default.
• W2996567573 hasAuthorship W2996567573A5037641879 @default.
• W2996567573 hasAuthorship W2996567573A5043815724 @default.
• W2996567573 hasAuthorship W2996567573A5045885141 @default.
• W2996567573 hasAuthorship W2996567573A5047441212 @default.
• W2996567573 hasAuthorship W2996567573A5063351719 @default.
• W2996567573 hasAuthorship W2996567573A5073029911 @default.
• W2996567573 hasAuthorship W2996567573A5089322497 @default.
• W2996567573 hasAuthorship W2996567573A5090537271 @default.
• W2996567573 hasBestOaLocation W29965675731 @default.
• W2996567573 hasConcept C115624301 @default.
• W2996567573 hasConcept C121332964 @default.
• W2996567573 hasConcept C147597530 @default.
• W2996567573 hasConcept C152365726 @default.
• W2996567573 hasConcept C178790620 @default.
• W2996567573 hasConcept C185592680 @default.
• W2996567573 hasConcept C187961010 @default.
• W2996567573 hasConcept C192386470 @default.
• W2996567573 hasConcept C192562407 @default.
• W2996567573 hasConcept C201194858 @default.
• W2996567573 hasConcept C2781203326 @default.
• W2996567573 hasConcept C32909587 @default.
• W2996567573 hasConcept C46141821 @default.
• W2996567573 hasConcept C55213715 @default.
• W2996567573 hasConcept C71240020 @default.
• W2996567573 hasConcept C75473681 @default.
• W2996567573 hasConcept C8010536 @default.
• W2996567573 hasConceptScore W2996567573C115624301 @default.
• W2996567573 hasConceptScore W2996567573C121332964 @default.
• W2996567573 hasConceptScore W2996567573C147597530 @default.
• W2996567573 hasConceptScore W2996567573C152365726 @default.
• W2996567573 hasConceptScore W2996567573C178790620 @default.
• W2996567573 hasConceptScore W2996567573C185592680 @default.

• next