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- W2996948493 abstract "In a flow microreactor, aryllithiums bearing a piperidylmethyl group were generated using n BuLi by precise residence time control and effective temperature control, and then selectively borylated with boronic esters such as 2‐isopropoxy‐4,4,5,5‐tetramethyl‐1,3,2‐dioxaborolane (BpinO i Pr) and trimethyl borate B(OMe) 3 by fast mixing. Moreover, the direct integration with Suzuki–Miyaura cross coupling were successfully achieved to obtain nitrogen‐containing biaryl compounds. The present method could be applied for the straightforward synthesis of the key intermediate of a bioactive component bearing a piperidylmethyl‐biphenyl framework." @default.
- W2996948493 created "2020-01-10" @default.
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- W2996948493 date "2020-01-29" @default.
- W2996948493 modified "2023-09-23" @default.
- W2996948493 title "Synthesis of Biaryls Having a Piperidylmethyl Group Based on Space Integration of Lithiation, Borylation, and Suzuki-Miyaura Coupling" @default.
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