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- W2996954232 endingPage "108" @default.
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- W2996954232 abstract "This review is devoted to the theoretic and synthetic aspects of asymmetric electrophilic substitution reactions at the stereogenic phosphorus center. The stereochemistry and mechanisms of electrophilic reactions are discussed—the substitution, addition and addition-elimination of many important reactions. The reactions of bimolecular electrophilic substitution SE2(P) proceed stereospecifically with the retention of absolute configuration at the phosphorus center, in contrast to the reactions of bimolecular nucleophilic substitution SN2(P), proceeding with inversion of absolute configuration. This conclusion was made based on stereochemical analysis of a wide range of trivalent phosphorus reactions with typical electrophiles and investigation of examples of a sizeable number of diverse compounds. The combination of stereospecific electrophilic reactions and stereoselective nucleophilic reactions is useful and promising for the further development of organophosphorus chemistry. The study of phosphoryl group transfer reactions is important for biological and molecular chemistry, as well as in studying mechanisms of chemical processes involving organophosphorus compounds. New versions of asymmetric electrophilic reactions applicable for the synthesis of enantiopure P-chiral secondary and tertiary phosphines are discussed." @default.
- W2996954232 created "2020-01-10" @default.
- W2996954232 creator A5006209051 @default.
- W2996954232 creator A5039651620 @default.
- W2996954232 date "2020-01-06" @default.
- W2996954232 modified "2023-10-16" @default.
- W2996954232 title "Asymmetric Electrophilic Reactions in Phosphorus Chemistry" @default.
- W2996954232 cites W107044078 @default.
- W2996954232 cites W1529983552 @default.
- W2996954232 cites W1551091947 @default.
- W2996954232 cites W1787501061 @default.
- W2996954232 cites W1926812470 @default.
- W2996954232 cites W1949685883 @default.
- W2996954232 cites W1963833173 @default.
- W2996954232 cites W1964658576 @default.
- W2996954232 cites W1966663491 @default.
- W2996954232 cites W1967161856 @default.
- W2996954232 cites W1968130667 @default.
- W2996954232 cites W1970679141 @default.
- W2996954232 cites W1970706297 @default.
- W2996954232 cites W1970869725 @default.
- W2996954232 cites W1973265868 @default.
- W2996954232 cites W1975682843 @default.
- W2996954232 cites W1975911768 @default.
- W2996954232 cites W1976054155 @default.
- W2996954232 cites W1977051443 @default.
- W2996954232 cites W1978698927 @default.
- W2996954232 cites W1982473065 @default.
- W2996954232 cites W1983062608 @default.
- W2996954232 cites W1984767616 @default.
- W2996954232 cites W1984790836 @default.
- W2996954232 cites W1987415780 @default.
- W2996954232 cites W1990070046 @default.
- W2996954232 cites W1991103517 @default.
- W2996954232 cites W1992179839 @default.
- W2996954232 cites W1995414866 @default.
- W2996954232 cites W1996140686 @default.
- W2996954232 cites W2000016386 @default.
- W2996954232 cites W2004057210 @default.
- W2996954232 cites W2005786129 @default.
- W2996954232 cites W2006092375 @default.
- W2996954232 cites W2007168800 @default.
- W2996954232 cites W2007487132 @default.
- W2996954232 cites W2007841380 @default.
- W2996954232 cites W2007889668 @default.
- W2996954232 cites W2013981315 @default.
- W2996954232 cites W2014138685 @default.
- W2996954232 cites W2015439246 @default.
- W2996954232 cites W2016359471 @default.
- W2996954232 cites W2017276950 @default.
- W2996954232 cites W2017990380 @default.
- W2996954232 cites W2019142825 @default.
- W2996954232 cites W2021122704 @default.
- W2996954232 cites W2021307147 @default.
- W2996954232 cites W2022577000 @default.
- W2996954232 cites W202337037 @default.
- W2996954232 cites W2027033941 @default.
- W2996954232 cites W2028351865 @default.
- W2996954232 cites W2030819161 @default.
- W2996954232 cites W2031310500 @default.
- W2996954232 cites W2031873281 @default.
- W2996954232 cites W2032000712 @default.
- W2996954232 cites W2035483535 @default.
- W2996954232 cites W2036439692 @default.
- W2996954232 cites W2038109973 @default.
- W2996954232 cites W2038798777 @default.
- W2996954232 cites W2039414682 @default.
- W2996954232 cites W2039704768 @default.
- W2996954232 cites W2040182081 @default.
- W2996954232 cites W2042168054 @default.
- W2996954232 cites W2043202402 @default.
- W2996954232 cites W2044038839 @default.
- W2996954232 cites W2044046997 @default.
- W2996954232 cites W2044462030 @default.
- W2996954232 cites W2047870969 @default.
- W2996954232 cites W2048755582 @default.
- W2996954232 cites W2050520718 @default.
- W2996954232 cites W2054925552 @default.
- W2996954232 cites W2056715470 @default.
- W2996954232 cites W2057081152 @default.
- W2996954232 cites W2057702685 @default.
- W2996954232 cites W2060889112 @default.
- W2996954232 cites W2062893003 @default.
- W2996954232 cites W2063859240 @default.
- W2996954232 cites W2068592533 @default.
- W2996954232 cites W2069132954 @default.
- W2996954232 cites W2072541503 @default.
- W2996954232 cites W2072655514 @default.
- W2996954232 cites W2072888590 @default.
- W2996954232 cites W2075614799 @default.
- W2996954232 cites W207586928 @default.
- W2996954232 cites W2076239965 @default.
- W2996954232 cites W2078413087 @default.
- W2996954232 cites W2078720251 @default.
- W2996954232 cites W2082384922 @default.
- W2996954232 cites W2083455098 @default.
- W2996954232 cites W2087562120 @default.
- W2996954232 cites W2088907863 @default.