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• W2997010355 abstract "The adsorption of CO2 by conventional liquid alkanolamine adsorbents does not meet the requirements for green-friendly development in industrial applications. In this work, we constructed NH2-β-CD-MOF for the first time through the amino-functionalization of the lowest-priced, readily available, and biocompatible β-CD. Subsequently, the samples were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, scanning electron microscopy, differential scanning calorimetry, thermogravimetric analysis, elemental analysis, and N2 adsorption/desorption. The CO2 adsorption capacity of NH2-β-CD-MOF was found to be 12.3 cm3/g, which is 10 times that of β-CD-MOF. In addition, NH2-β-CD-MOF has outstanding selective adsorption of CO2/N2 (947.52) compared with the reported materials. The adsorption mechanism of CO2 was analyzed by X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. Furthermore, we have found that NH2-β-CD-MOF has better water stability relative to β-CD-MOF and γ-CD-MOF, and it can be recycled by an ultrasonic method." @default.
• W2997010355 created "2020-01-10" @default.
• W2997010355 creator A5002828648 @default.
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• W2997010355 creator A5056445211 @default.
• W2997010355 creator A5087785686 @default.
• W2997010355 date "2019-12-23" @default.
• W2997010355 modified "2023-10-06" @default.
• W2997010355 title "Amino-Functionalized β-Cyclodextrin to Construct Green Metal–Organic Framework Materials for CO₂ Capture" @default.
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• W2997010355 doi "https://doi.org/10.1021/acsami.9b20003" @default.
• W2997010355 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31867947" @default.
• W2997010355 hasPublicationYear "2019" @default.
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