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- W2997127329 abstract "Ion conductors of light alkaline metals based on earth-abundant elements are important components for all-solid-state batteries. The new sodium-rich phosphidosilicate Na2SiP2 was synthesized by solid state reaction of stoichiometric amounts of the elements at 973 K and characterized by single-crystal X-ray diffraction (space group Pccn (no. 56), a = 12.7929(5) Å, b = 22.3109(9) Å, c = 6.0522(2) Å and Z = 16) and solid-state NMR under MAS conditions. The compound forms dark-red twinned crystals, and its crystal structure contains edge-sharing SiP4 tetrahedra connected to infinite ∞1[SiP4/2] chains. The sodium ions between the chains are fairly mobile. Electrochemical impedance spectroscopy shows a total ionic conductivity of σ(Na+, 373 K) = 2.3 ? 10–6 Scm–1 with an activation energy of Ea = 0.43 eV, and the galvanostatic polarization reveals mixed conduction behavior with a transference number of 0.8." @default.
- W2997127329 created "2020-01-10" @default.
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- W2997127329 date "2020-02-06" @default.
- W2997127329 modified "2023-09-23" @default.
- W2997127329 title "Synthesis and Structure of the Sodium Phosphidosilicate Na <sub>2</sub> SiP <sub>2</sub>" @default.
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- W2997127329 doi "https://doi.org/10.1002/ejic.201901083" @default.
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