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- W2997275228 abstract "Summary of main observation and conclusion An electrochemical synthesis of oxazol‐2‐ones and imidazol‐2‐ones has been developed via 5‐ exo ‐ dig cyclization of propargylic carbamates‐ and ureas‐derived amidyl radicals. The electrosynthesis relies on the dual function of 2,2,6,6‐tetramethylpiperidin‐ 1‐yl)oxyl (TEMPO) as a redox mediator for amidyl radical formation and an oxygen atom donor. The reactions are conducted under mild conditions using a simple setup and provide convenient access to functionalized oxazol‐2‐ones and imidazol‐2‐ones from readily available materials." @default.
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- W2997275228 date "2020-02-21" @default.
- W2997275228 modified "2023-09-30" @default.
- W2997275228 title "Electrochemically Enabled Intramolecular Aminooxygenation of Alkynes <i>via</i> Amidyl Radical Cyclization" @default.
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- W2997275228 doi "https://doi.org/10.1002/cjoc.201900500" @default.
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