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• W2997456411 abstract "Synthesis of novel mono- and di-O-protected l-arabinofuranoside derivatives was described via regioselective base-catalyzed acylations of methyl α- and β-l-arabinofuranosides with acyl chlorides. A new method for selective 3(2)-O-acylation of 5-O-silyl (trityl) l-arabinofuranosides was investigated based upon generation of organoboron compounds using l-Selectride and subsequent reaction of salt carbohydrate species with pivaloyl or 4-chlorobenzoyl chloride as the electrophile. Syntheses of methyl 2,3-anhydro-l-furanosides were accomplished from selectively protected methyl l-arabinofuranosides. 2(3)-Deoxy-l-pentofuranosides, including 2-deoxy-l-ribofuranoside, and their 5-O-blocked derivatives were prepared by stereoselective reductions of 2,3-anhydro-l-furanosides with l-Selectride." @default.
• W2997456411 created "2020-01-10" @default.
• W2997456411 creator A5030609193 @default.
• W2997456411 date "2020-02-01" @default.
• W2997456411 modified "2023-09-24" @default.
• W2997456411 title "Regioselective and stereocontrolled syntheses of protected L-glycosides from L-arabinofuranosides" @default.
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• W2997456411 doi "https://doi.org/10.1016/j.carres.2019.107901" @default.
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